A novel 3-D chiral organic–inorganic hybrid zinc vanadate, [Zn2(μ-en)V2O7]n (1, en = ethylenediamine), which is assembled from rare 1-D [(ZnO3)(μ-en)(ZnO4)]n helical chains and dimeric [V2O7] units, has been hydrothermally synthesized. The theoretical band structure and optical properties have also been studied.
Dalton Transactions
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