Structural and in situ NMR spectroscopic studies show that N–H deprotonation, B–N bond cleavage and B–N bond formation can occur in the stoichiometric and catalytic reactions of LiAlH4 with Me2NHBH3.
The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor
3.838
48 Issues per Year
Indexed in MEDLINE
Paper
Stoichiometric and catalytic reactions of LiAlH4 with Me2NHBH3
Show Affiliations
Hide Affiliations
*
Corresponding authors
a
Chemistry Department, Cambridge University, Lensfield Road, Cambridge CB2 1EW, UK
E-mail: dsw1000@cam.ac.uk ;
Fax: +44 (0)1223 336362 ;
Tel: +44 (0)1223 763122
E-mail: dsw1000@cam.ac.uk ;
Fax: +44 (0)1223 336362 ;
Tel: +44 (0)1223 763122
Dalton Trans., 2013,42, 6337-6343
DOI: 10.1039/C2DT32569A
Received 26 Oct 2012, Accepted 13 Dec 2012
First published online 18 Dec 2012
Dalton Transactions
- Information Point
Supplementary Info
-
Supplementary information
PDF (702K) -
Crystal structure data
TXT (47K)