Heterometallic appended {MMnIII4} cubanes encapsulated by lacunary polytungstate ligands

Hai-Hong Wu; Shuang Yao; Zhi-Ming Zhang; Yang-Guang Li; You Song; Zhu-Jun Liu; Xin-Bao Han; En-Bo Wang

doi:10.1039/C2DT32318D

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Heterometallic appended {MMn^III₄} cubanes encapsulated by lacunary polytungstate ligands†

Hai-Hong Wu,^a Shuang Yao,^c Zhi-Ming Zhang,*^a Yang-Guang Li,^a You Song,*^b Zhu-Jun Liu,^a Xin-Bao Han^a and En-Bo Wang*^a

Author affiliations

* Corresponding authors

^a Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Ren Min Street No. 5268, Changchun, Jilin 130024, P. R. China
E-mail: zhangzm178@nenu.edu.cn, wangeb889@nenu.edu.cn

^b State Key Laboratory of Coordination Chemistry, Nanjing University, 22 Hankou Road, Nanjing 210093, P. R. China
E-mail: yousong@nju.edu.cn

^c College of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun, Jilin 130022, P. R. China

Abstract

The heterometallic appended {MMn^III₄} (M = Dy³⁺ and K⁺) cubanes were firstly trapped by two diamagnetic POM shells, which were robust enough to construct inorganic crystalline tubular materials. Magnetic study reveals the presence of a SMM-like slow magnetic relaxation feature in the heterometallic cluster-containing POM.

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Article information

DOI: https://doi.org/10.1039/C2DT32318D
Article type: Communication
Submitted: 02 Oct 2012
Accepted: 26 Oct 2012
First published: 26 Oct 2012

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Dalton Trans., 2013,42, 342-346

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Heterometallic appended {MMn^III₄} cubanes encapsulated by lacunary polytungstate ligands

H. Wu, S. Yao, Z. Zhang, Y. Li, Y. Song, Z. Liu, X. Han and E. Wang, Dalton Trans., 2013, 42, 342 DOI: 10.1039/C2DT32318D

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