An ion-exchange route for the synthesis of hierarchical In2S3/ZnIn2S4 bulk composite and its photocatalytic activity under visible-light irradiation

Zongwei Mei; Shuxin Ouyang; Dai-Ming Tang; Tetsuya Kako; Dmitri Golberg; Jinhua Ye

doi:10.1039/C2DT32271D

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Dalton Transactions

Issue 8, 2013

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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An ion-exchange route for the synthesis of hierarchical In₂S₃/ZnIn₂S₄ bulk composite and its photocatalytic activity under visible-light irradiation

Zongwei Mei,^a^b Shuxin Ouyang,*^b^d Dai-Ming Tang,^c Tetsuya Kako,^a^b Dmitri Golberg^c and Jinhua Ye*^a^b^c^d

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Department of Chemistry, Graduate School of Science, Hokkaido University, Sapporo, Japan

Research Unit for Environmental Remediation Materials, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
E-mail: OUYANG.Shuxin@nims.go.jp ;
Fax: (+81)-29-860-4958

International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan

TU-NIMS Joint Research Center, School of Materials Science and Engineering, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, P. R. China

Dalton Trans., 2013,42, 2687-2690

DOI: 10.1039/C2DT32271D
Received 27 Sep 2012, Accepted 20 Dec 2012
First published online 20 Dec 2012

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In₂S₃/ZnIn₂S₄ bulk composite was successfully synthesized through an ion-exchange route using NaInS₂ as a precursor. Compared with the constituent pure component (In₂S₃ or ZnIn₂S₄), the photocatalytic H₂ evolution of the composite was greatly enhanced because of the efficient separation and migration of photoexcited carriers (electrons and holes) at the interface of the bulk composite.

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Zongwei Mei
Shuxin Ouyang
Dai-Ming Tang
Tetsuya Kako
Dmitri Golberg
Jinhua Ye

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Dalton Transactions

An ion-exchange route for the synthesis of hierarchical In₂S₃/ZnIn₂S₄ bulk composite and its photocatalytic activity under visible-light irradiation

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An ion-exchange route for the synthesis of hierarchical In2S3/ZnIn2S4 bulk composite and its photocatalytic activity under visible-light irradiation

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An ion-exchange route for the synthesis of hierarchical In₂S₃/ZnIn₂S₄ bulk composite and its photocatalytic activity under visible-light irradiation