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Issue 2, 2013
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Two new scorpionate oxomolybdenum(VI)–poly(pyrazolyl)borate complexes: synthesis, structure, and catalytic performance in the oxidation of cyclohexane

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Abstract

Two new oxomolybdenum(VI) complexes [(TpMoO2)2(μ-O)]·H2O (1) and (Tp4-IMoO2)2(μ-O) (2) were synthesized and characterized by elemental analysis, IR spectra, UV-Vis spectroscopy, powder X-ray diffraction, single-crystal X-ray diffraction and thermogravimetric analyses (TG). In addition, the catalytic performances of complexes 1 and 2 were studied firstly on the oxidation reaction of cyclohexane at room temperature.

Graphical abstract: Two new scorpionate oxomolybdenum(vi)–poly(pyrazolyl)borate complexes: synthesis, structure, and catalytic performance in the oxidation of cyclohexane

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Publication details

The article was received on 06 Aug 2012, accepted on 03 Oct 2012 and first published on 04 Oct 2012


Article type: Communication
DOI: 10.1039/C2DT32184J
Citation: Dalton Trans., 2013,42, 359-363
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    Two new scorpionate oxomolybdenum(VI)–poly(pyrazolyl)borate complexes: synthesis, structure, and catalytic performance in the oxidation of cyclohexane

    N. Xing, H. Shan, X. Tian, Q. Yao, L. Xu, Y. Xing and Z. Shi, Dalton Trans., 2013, 42, 359
    DOI: 10.1039/C2DT32184J

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