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Issue 3, 2013
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TICT fluorescence of N-borylated 2,5-diarylpyrroles: a gear like dual motion in the excited state

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Abstract

A significantly red-shifted fluorescence and a high fluorescence quantum yield for the emission from the twisted intramolecular charge transfer (TICT) state are attained in new aminoboranes, N-borylated 2,5-diarylpyrroles. A gear like dual structural motion in the excited state is responsible for their large Stokes shifts.

Graphical abstract: TICT fluorescence of N-borylated 2,5-diarylpyrroles: a gear like dual motion in the excited state

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Publication details

The article was received on 15 Sep 2012, accepted on 08 Oct 2012 and first published on 09 Oct 2012


Article type: Communication
DOI: 10.1039/C2DT32134C
Citation: Dalton Trans., 2013,42, 620-624
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    TICT fluorescence of N-borylated 2,5-diarylpyrroles: a gear like dual motion in the excited state

    T. Taniguchi, J. Wang, S. Irle and S. Yamaguchi, Dalton Trans., 2013, 42, 620
    DOI: 10.1039/C2DT32134C

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