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Issue 1, 2013
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Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water—pH dependence and effects of buffers

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Abstract

Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1 : 1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated.

Graphical abstract: Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water—pH dependence and effects of buffers

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Publication details

The article was received on 31 Aug 2012, accepted on 08 Oct 2012 and first published on 09 Oct 2012


Article type: Communication
DOI: 10.1039/C2DT32009F
Citation: Dalton Trans., 2013,42, 67-70
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    Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water—pH dependence and effects of buffers

    L. R. Hill, T. J. Sørensen, O. A. Blackburn, A. Brown, P. D. Beer and S. Faulkner, Dalton Trans., 2013, 42, 67
    DOI: 10.1039/C2DT32009F

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