Scaling down the size of BaLnF5 nanocrystals (Ln = La, Gd, and Lu) with the Ln3+ size

Shyam Sarkar; Chanchal Hazra; Venkataramanan Mahalingam

doi:10.1039/C2DT31915B

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Dalton Transactions

Issue 1, 2013

The international journal for inorganic, organometallic and bioinorganic chemistry

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Scaling down the size of BaLnF₅ nanocrystals (Ln = La, Gd, and Lu) with the Ln³⁺ size

Shyam Sarkar,^a Chanchal Hazra^a and Venkataramanan Mahalingam*^a

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Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER), Kolkata, Mohanpur, India
E-mail: mvenkataramanan@yahoo.com ;
Fax: +91-33-25873020 ;
Tel: +91 (0) 9007603474

Dalton Trans., 2013,42, 63-66

DOI: 10.1039/C2DT31915B
Received 21 Aug 2012, Accepted 18 Oct 2012
First published online 22 Oct 2012

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Monodispersed Yb³⁺(20%)/Er³⁺(2%)-doped BaLnF₅ (Ln = La, Gd, Lu) nanocrystals were synthesized by a thermal decomposition method. The study reveals that the size of the nanocrystals scales down with the Ln³⁺ size without affecting the phase and shape of the nanocrystals. This is supported by the microscopic and optical properties.

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Scaling down the size of BaLnF₅ nanocrystals (Ln = La, Gd, and Lu) with the Ln³⁺ size

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Scaling down the size of BaLnF5 nanocrystals (Ln = La, Gd, and Lu) with the Ln3+ size

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Scaling down the size of BaLnF₅ nanocrystals (Ln = La, Gd, and Lu) with the Ln³⁺ size