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Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo, Japan
; Fax: +81 3 3817 1902
; Tel: +81 3 3817 1902
Dalton Trans., 2013,42, 625-629
17 Aug 2012,
01 Nov 2012
First published online
20 Nov 2012
Four platinum(II) complexes bearing a boron-based PBP pincer ligand and chloride, hydride, triflate, and bis(trifluoromethanesulfonyl)imide were synthesized and structurally characterized. PBP-platinum chloride was proven to be an active catalyst for the hydrosilylation reaction using 1-decene and triethylsilane.
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