Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene

Hayato Ogawa; Makoto Yamashita

doi:10.1039/C2DT31892J

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Dalton Transactions

Issue 3, 2013

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene

Hayato Ogawa^a and Makoto Yamashita*^a

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Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo, Japan
E-mail: makoto@oec.chem.chuo-u.ac.jp ;
Fax: +81 3 3817 1902 ;
Tel: +81 3 3817 1902

Dalton Trans., 2013,42, 625-629

DOI: 10.1039/C2DT31892J
Received 17 Aug 2012, Accepted 01 Nov 2012
First published online 20 Nov 2012

This article is part of themed collection: Boranes and borohydrides

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Abstract
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Four platinum(II) complexes bearing a boron-based PBP pincer ligand and chloride, hydride, triflate, and bis(trifluoromethanesulfonyl)imide were synthesized and structurally characterized. PBP-platinum chloride was proven to be an active catalyst for the hydrosilylation reaction using 1-decene and triethylsilane.