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Issue 3, 2013
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Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene

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Abstract

Four platinum(II) complexes bearing a boron-based PBP pincer ligand and chloride, hydride, triflate, and bis(trifluoromethanesulfonyl)imide were synthesized and structurally characterized. PBP-platinum chloride was proven to be an active catalyst for the hydrosilylation reaction using 1-decene and triethylsilane.

Graphical abstract: Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene

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The article was received on 17 Aug 2012, accepted on 01 Nov 2012 and first published on 20 Nov 2012


Article type: Communication
DOI: 10.1039/C2DT31892J
Citation: Dalton Trans., 2013,42, 625-629
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    Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene

    H. Ogawa and M. Yamashita, Dalton Trans., 2013, 42, 625
    DOI: 10.1039/C2DT31892J

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