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Issue 4, 2013
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Easily accessible, hydrocarbon-soluble, crystalline, anhydrous lanthanide (Nd, La, and Y) phosphates

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Abstract

Nd, La and Y triphosphates were prepared via the reaction of potassium ionol ethyl phosphate with the corresponding lanthanide nitrates or chlorides in water. According to the X-ray diffraction data, the recrystallised reaction products were dimers. The products did not contain water, were readily soluble in hydrocarbon solvents and demonstrated promising catalytic properties in the polymerisation of butadiene and DL-dilactide.

Graphical abstract: Easily accessible, hydrocarbon-soluble, crystalline, anhydrous lanthanide (Nd, La, and Y) phosphates

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Publication details

The article was received on 09 Jul 2012, accepted on 05 Oct 2012 and first published on 09 Oct 2012


Article type: Paper
DOI: 10.1039/C2DT31505J
Citation: Dalton Trans., 2013,42, 1223-1230
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    Easily accessible, hydrocarbon-soluble, crystalline, anhydrous lanthanide (Nd, La, and Y) phosphates

    I. E. Nifant'ev, A. N. Tavtorkin, A. V. Shlyahtin, S. A. Korchagina, I. F. Gavrilenko, N. N. Glebova and A. V. Churakov, Dalton Trans., 2013, 42, 1223
    DOI: 10.1039/C2DT31505J

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