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Issue 1, 2013
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Single-molecule magnet based on a C-type polyoxomolybdate with an S = 11 ground state: [Fe5CoMo22As2O85(H2O)]15−

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Abstract

A C-type polyoxomolybdate containing a mixed-transition metal cluster Fe5Co has been prepared as an ammonium salt, (NH4)15[Fe5CoMo22As2O85(H2O)]·15H2O (1). Interestingly, the magnetism measurements show that the compound exhibits not only an overall ferromagnetic cluster with a large spin ground state of S = 11 but also the behavior of single-molecule magnets.

Graphical abstract: Single-molecule magnet based on a C-type polyoxomolybdate with an S = 11 ground state: [Fe5CoMo22As2O85(H2O)]15−

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Publication details

The article was received on 21 Jun 2012, accepted on 19 Oct 2012 and first published on 22 Oct 2012


Article type: Communication
DOI: 10.1039/C2DT31331F
Citation: Dalton Trans., 2013,42, 58-62
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    Single-molecule magnet based on a C-type polyoxomolybdate with an S = 11 ground state: [Fe5CoMo22As2O85(H2O)]15−

    Y. Zhen, B. Liu, L. Li, D. Wang, Y. Ma, H. Hu, S. Gao and G. Xue, Dalton Trans., 2013, 42, 58
    DOI: 10.1039/C2DT31331F

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