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Issue 11, 2013
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Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation

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Abstract

Gold(III) complexes of type [AuCl22-RC(R′pz)3}]Cl [R = R′ = H (1), R = CH2OH, R′ = H (2) and R = H, R′ = 3,5-Me2 (3), pz = pyrazol-1-yl] were supported on carbon materials (activated carbon, carbon xerogel and carbon nanotubes) and used for the oxidation of cyclohexane to cyclohexanol and cyclohexanone, with aqueous H2O2, under mild conditions.

Graphical abstract: Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation

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Publication details

The article was received on 28 Jul 2013, accepted on 25 Aug 2013 and first published on 28 Aug 2013


Article type: Paper
DOI: 10.1039/C3CY00552F
Citation: Catal. Sci. Technol., 2013,3, 3056-3069
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    Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation

    M. P. de Almeida, L. M. D. R. S. Martins, S. A. C. Carabineiro, T. Lauterbach, F. Rominger, A. S. K. Hashmi, A. J. L. Pombeiro and J. L. Figueiredo, Catal. Sci. Technol., 2013, 3, 3056
    DOI: 10.1039/C3CY00552F

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