Issue 5, 2013

Regioselective Pd-catalyzed hydroamination of substituted dienes

Abstract

The regioselective addition of hydrazones and related N-nucleophiles to substituted terpene-based substrates can be steered to either 1,2- or 1,4-addition products, making this a potentially powerful protocol for the preparation of amines from biorelevant feedstocks via C–N bond formation.

Graphical abstract: Regioselective Pd-catalyzed hydroamination of substituted dienes

Article information

Article type
Paper
Submitted
09 Jan 2013
Accepted
18 Feb 2013
First published
19 Feb 2013
This article is Open Access

Catal. Sci. Technol., 2013,3, 1375-1379

Regioselective Pd-catalyzed hydroamination of substituted dienes

A. Perrier, M. Ferreira, J. N. H. Reek and J. I. van der Vlugt, Catal. Sci. Technol., 2013, 3, 1375 DOI: 10.1039/C3CY00024A

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