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Issue 3, 2013
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Dismantling the salen framework: design of new asymmetric silylcyanation catalysts

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Abstract

A series of novel chiral phenoxyimine Al(III) complexes catalyzes asymmetric addition of SiMe3CN to a broad range of aldehydes with high yields and good to excellent enantioselectivities in the presence of a Lewis base.

Graphical abstract: Dismantling the salen framework: design of new asymmetric silylcyanation catalysts

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Publication details

The article was received on 16 Oct 2012, accepted on 30 Nov 2012 and first published on 30 Nov 2012


Article type: Communication
DOI: 10.1039/C2CY20818K
Citation: Catal. Sci. Technol., 2013,3, 580-583
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    Dismantling the salen framework: design of new asymmetric silylcyanation catalysts

    J. Ternel, P. Roussel, F. Agbossou-Niedercorn and R. M. Gauvin, Catal. Sci. Technol., 2013, 3, 580
    DOI: 10.1039/C2CY20818K

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