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Issue 4, 2013
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Medium and high oxidation state metal/non-metal fluoride and oxide–fluoride complexes with neutral donor ligands

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Abstract

While most high and medium oxidation state (O.S. ≥ 3) metal and non-metal fluorides and oxide fluorides are strong Lewis acids, exploration of their coordination chemistry with neutral ligands has been limited and mostly non-systematic. This is despite the very different properties conferred on the acceptor centre by the small electronegative fluoride ligands compared to the heavier halides. This article sets out these key differences, discusses possible synthetic routes, the key characterisation techniques, and appropriate bonding models. Current knowledge of the coordination chemistry of d, f and p-block fluorides and oxide fluorides with neutral ligands (with donor atoms drawn from Groups 15 and 16 and including N-heterocyclic carbenes) is then presented and discussed, and the differences in properties compared to complexes containing the heavier halides are illustrated. The emphasis is on work published post 1990, but earlier work is also included as essential background and where no more recent information exists. Attention is drawn to unexplored areas meriting investigation and to possible applications of these complexes.

Graphical abstract: Medium and high oxidation state metal/non-metal fluoride and oxide–fluoride complexes with neutral donor ligands

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Publication details

The article was received on 16 Jul 2012 and first published on 26 Sep 2012


Article type: Review Article
DOI: 10.1039/C2CS35263J
Citation: Chem. Soc. Rev., 2013,42, 1460-1499
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    Medium and high oxidation state metal/non-metal fluoride and oxide–fluoride complexes with neutral donor ligands

    S. L. Benjamin, W. Levason and G. Reid, Chem. Soc. Rev., 2013, 42, 1460
    DOI: 10.1039/C2CS35263J

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