Transition metal-catalyzed oxidative dehydrogenative coupling reactions of Caryl–H bonds with Cvinyl–H bonds to generate a Caryl–Cvinyl bonds have been well developed in recent decades. However, only a few studies have focused on the direct Cvinyl–Cvinyl bond formation via double Cvinyl–H bond activation. Recent developments in this active area have been highlighted in this tutorial review.
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