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Issue 44, 2013
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CH2OO Criegee biradical yields following photolysis of CH2I2 in O2

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Abstract

Yields of CH2OO and CH2IO2 from the reaction of CH2I radicals with O2 are reported as a function of total pressure, [N2] and [O2] at T = 295 K using three complementary methods. Results from the three methods are similar, with no observed additional dependence on [O2]. The CH2I + O2 reaction has a yield of ∼18% CH2OO at atmospheric pressure.

Graphical abstract: CH2OO Criegee biradical yields following photolysis of CH2I2 in O2

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Publication details

The article was received on 13 Jun 2013, accepted on 06 Sep 2013 and first published on 12 Sep 2013


Article type: Communication
DOI: 10.1039/C3CP52466C
Citation: Phys. Chem. Chem. Phys., 2013,15, 19119-19124
  • Open access: Creative Commons BY license
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    CH2OO Criegee biradical yields following photolysis of CH2I2 in O2

    D. Stone, M. Blitz, L. Daubney, T. Ingham and P. Seakins, Phys. Chem. Chem. Phys., 2013, 15, 19119
    DOI: 10.1039/C3CP52466C

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