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Issue 26, 2013
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Multinuclear (67Zn, 119Sn and 65Cu) NMR spectroscopy – an ideal technique to probe the cationic ordering in Cu2ZnSnS4 photovoltaic materials

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Abstract

For the very first time, 67Zn, 119Sn and 65Cu NMR investigations have been carried out on Cu2ZnSnS4 derivatives (CZTS) for photovoltaic applications. NMR spectroscopy is shown to be sensitive enough to probe the Cu/Zn disorder within the kesterite structure of the studied compounds. In addition, reference spectra of Cu2ZnSnS4 are provided, and experimental 67Zn and 65Cu parameters are compared with ab initio calculations.

Graphical abstract: Multinuclear (67Zn, 119Sn and 65Cu) NMR spectroscopy – an ideal technique to probe the cationic ordering in Cu2ZnSnS4 photovoltaic materials

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Publication details

The article was received on 28 Mar 2013, accepted on 20 May 2013 and first published on 23 May 2013


Article type: Communication
DOI: 10.1039/C3CP51320C
Citation: Phys. Chem. Chem. Phys., 2013,15, 10722-10725
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    Multinuclear (67Zn, 119Sn and 65Cu) NMR spectroscopy – an ideal technique to probe the cationic ordering in Cu2ZnSnS4 photovoltaic materials

    L. Choubrac, M. Paris, A. Lafond, C. Guillot-Deudon, X. Rocquefelte and S. Jobic, Phys. Chem. Chem. Phys., 2013, 15, 10722
    DOI: 10.1039/C3CP51320C

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