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Issue 21, 2013
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Strong-pump strong-probe spectroscopy: effects of higher excited electronic states

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Abstract

The present paper is devoted to the simulation of (integral and dispersed) pump–probe signals in the nonperturbative regime for a series of material systems with multiple electronic states and excited-state absorption. We show that strong-pump strong-probe spectroscopy permits the probing of vibrational wavepackets in high-lying and/or short-lived excited electronic states with a time resolution which is not limited by the pulse durations. The field strength can be regarded as an additional experimentally controllable parameter, which can be tuned to maximize the spectroscopic information for a given material system.

Graphical abstract: Strong-pump strong-probe spectroscopy: effects of higher excited electronic states

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Publication details

The article was received on 11 Dec 2012, accepted on 21 Mar 2013 and first published on 22 Mar 2013


Article type: Paper
DOI: 10.1039/C3CP44454F
Citation: Phys. Chem. Chem. Phys., 2013,15, 8119-8131
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    Strong-pump strong-probe spectroscopy: effects of higher excited electronic states

    M. F. Gelin, D. Egorova and W. Domcke, Phys. Chem. Chem. Phys., 2013, 15, 8119
    DOI: 10.1039/C3CP44454F

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