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Issue 8, 2013
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Low-cost industrially available molybdenum boride and carbide as “platinum-like” catalysts for the hydrogen evolution reaction in biphasic liquid systems

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Abstract

Rarely reported low-cost molybdenum boride and carbide microparticles, both of which are available in abundant quantities due to their widespread use in industry, adsorb at aqueous acid–1,2-dichloroethane interfaces and efficiently catalyse the hydrogen evolution reaction in the presence of the organic electron donor – decamethylferrocene. Kinetic studies monitoring biphasic reactions by UV/vis spectroscopy, and further evidence provided by gas chromatography, highlight (a) their superior rates of catalysis relative to other industrially significant transition metal carbides and silicides, as well as a main group refractory compound, and (b) their highly comparable rates of catalysis to Pt microparticles of similar dimensions. Insight into the catalytic processes occurring for each adsorbed microparticle was obtained by voltammetry at the liquid–liquid interface.

Graphical abstract: Low-cost industrially available molybdenum boride and carbide as “platinum-like” catalysts for the hydrogen evolution reaction in biphasic liquid systems

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Publication details

The article was received on 14 Dec 2012, accepted on 18 Dec 2012 and first published on 22 Jan 2013


Article type: Paper
DOI: 10.1039/C2CP44522K
Citation: Phys. Chem. Chem. Phys., 2013,15, 2847-2857
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    Low-cost industrially available molybdenum boride and carbide as “platinum-like” catalysts for the hydrogen evolution reaction in biphasic liquid systems

    M. D. Scanlon, X. Bian, H. Vrubel, V. Amstutz, K. Schenk, X. Hu, B. Liu and H. H. Girault, Phys. Chem. Chem. Phys., 2013, 15, 2847
    DOI: 10.1039/C2CP44522K

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