Issue 26, 2013

A microporous metal–organic framework with Lewis basic pyridyl sites for selective gas separation of C2H2/CH4 and CO2/CH4 at room temperature

Abstract

A microporous metal–organic framework [Eu(PDC)1.5(DMF)]·(DMF)0.5(H2O)0.5 (UTSA-5, PDC = 3,5-pyridinedicarboxylate) with pyridyl sites on the pore surface has been realized to exhibit high C2H2/CH4 and CO2/CH4 separation at room temperature.

Graphical abstract: A microporous metal–organic framework with Lewis basic pyridyl sites for selective gas separation of C2H2/CH4 and CO2/CH4 at room temperature

Supplementary files

Article information

Article type
Paper
Submitted
13 Mar 2013
Accepted
22 Apr 2013
First published
25 Apr 2013

CrystEngComm, 2013,15, 5232-5235

A microporous metal–organic framework with Lewis basic pyridyl sites for selective gas separation of C2H2/CH4 and CO2/CH4 at room temperature

G. Chen, Z. Zhang, S. Xiang and B. Chen, CrystEngComm, 2013, 15, 5232 DOI: 10.1039/C3CE40452H

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