Two isostructural amine-functionalized 3D self-penetrating microporous MOFs exhibiting high sorption selectivity for CO2

Bo Liu; Ruili Zhao; Guoping Yang; Lei Hou; Yao-Yu Wang; Qi-Zhen Shi

doi:10.1039/C3CE26800D

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Two isostructural amine-functionalized 3D self-penetrating microporous MOFs exhibiting high sorption selectivity for CO₂†

Bo Liu,^a Ruili Zhao,^a Guoping Yang,^a Lei Hou,^a Yao-Yu Wang*^a and Qi-Zhen Shi^a

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* Corresponding authors

^a Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, China
E-mail: wyaoyu@nwu.edu.cn
Tel: +86 29 88302604

Abstract

Two isostructural 3D microporous metal–organic frameworks, which show a 6-connected (4⁸·6⁶·8) self-penetrating net, contain two different narrow-sized channels functionalized by amino groups on the pore surface. In particular, both of them show exceptional stability and a high selectivity for CO₂ over N₂ at 298 K.

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Article information

DOI: https://doi.org/10.1039/C3CE26800D
Article type: Communication
Submitted: 02 Nov 2012
Accepted: 15 Jan 2013
First published: 16 Jan 2013

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CrystEngComm, 2013,15, 2057-2060

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Two isostructural amine-functionalized 3D self-penetrating microporous MOFs exhibiting high sorption selectivity for CO₂

B. Liu, R. Zhao, G. Yang, L. Hou, Y. Wang and Q. Shi, CrystEngComm, 2013, 15, 2057 DOI: 10.1039/C3CE26800D

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