A 1 : 1 intercluster compound consisting of +6 and −6 charged RhIII4ZnII4 octanuclear cations and anions with aminothiolate ligands

Nobuto Yoshinari; Ukyo Yamashita; Takumi Konno

doi:10.1039/C3CE41800F

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A 1 : 1 intercluster compound consisting of +6 and −6 charged Rh^III₄Zn^II₄ octanuclear cations and anions with aminothiolate ligands†

Nobuto Yoshinari,^a Ukyo Yamashita^a and Takumi Konno*^a

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^a Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka, Japan
E-mail: konno@chem.sci.osaka-u.ac
Fax: +81 6 6850 5765
Tel: +81 6 6850 5765

Abstract

The first example of a 1 : 1 metal–organic intercluster compound with +6 charged cations and −6 charged anions was synthesized from [Zn₄O{Rh(aet)₃}₄]⁶⁺ (aet = 2-aminoethanethiolate) and [Zn₄O{Rh(L-cys)₃}₄]⁶⁻ (L-cys = L-cysteinate). Its structure was determined by single-crystal X-ray crystallography, which revealed the formation of a diamondoid (dia) hydrogen-bonding network of the cluster anions, accommodating the cluster cations in its cavities.

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Article information

DOI: https://doi.org/10.1039/C3CE41800F
Article type: Paper
Submitted: 07 Sep 2013
Accepted: 22 Sep 2013
First published: 27 Sep 2013

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CrystEngComm, 2013,15, 10016-10019

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A 1 : 1 intercluster compound consisting of +6 and −6 charged Rh^III₄Zn^II₄ octanuclear cations and anions with aminothiolate ligands

N. Yoshinari, U. Yamashita and T. Konno, CrystEngComm, 2013, 15, 10016 DOI: 10.1039/C3CE41800F

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