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Issue 45, 2013
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Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2

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Abstract

There are relatively few metal–organic framework materials that are robust enough to survive post-synthetic modification of their structures. We present test modifications of Ti-MIL125-NH2 leading towards tuning of the porous and catalytic properties of the material. We also present the first use of a mild amide synthesis method for post-synthetic modification.

Graphical abstract: Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2

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Publication details

The article was received on 07 Jul 2013, accepted on 30 Aug 2013 and first published on 02 Sep 2013


Article type: Communication
DOI: 10.1039/C3CE41332B
Citation: CrystEngComm, 2013,15, 9368-9371
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    Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2

    A. P. Smalley, D. G. Reid, J. C. Tan and G. O. Lloyd, CrystEngComm, 2013, 15, 9368
    DOI: 10.1039/C3CE41332B

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