Issue 9, 2013
From the journal:

CrystEngComm

Novel (4,8)-connected scu coordination framework constructed by tetrakis(4-benzoic acid)ethylene†

Hao-Ling Sun,*a   Rui Jiang,a   Zongsheng Li,b   Yong Qiang Donga  and  Miao Du*c  

* Corresponding authors

a Department of Chemistry and Beijing Key Laboratory of Energy Conversion and Storage Materials, Beijing Normal University, Beijing 100875, P. R. China
E-mail: haolingsun@bnu.edu.cn

b College of Safety and Environment Engineering, Capital University of Economics and Business, Beijing 100070, P. R. China

c College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Tianjin Normal University, Tianjin 300387, P. R. China
E-mail: dumiao@public.tpt.tj.cn

Abstract

A novel (4,8)-connected scu {[Co(tbe)0.5(H2O)2]·0.5H2O} framework has been built by using a predesigned octahedral node of tetrakis(4-benzoic acid)ethylene. The magneto-structural relation study indicates weak anti-ferromagnetic coupling between metal ions transmitted by syn–anti carboxylate pathway due to the non-planarity of the Co–O–C–O–Co unit.

Graphical abstract: Novel (4,8)-connected scu coordination framework constructed by tetrakis(4-benzoic acid)ethylene

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Article information

DOI
https://doi.org/10.1039/C2CE26761F
Article type
Communication
Submitted
26 Oct 2012
Accepted
11 Dec 2012
First published
12 Dec 2012

CrystEngComm, 2013,15, 1669-1672

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Novel (4,8)-connected scu coordination framework constructed by tetrakis(4-benzoic acid)ethylene

H. Sun, R. Jiang, Z. Li, Y. Q. Dong and M. Du, CrystEngComm, 2013, 15, 1669 DOI: 10.1039/C2CE26761F

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