Screening and evaluating aminated cationic functional moieties for potential CO2 capture applications using an anionic MOF scaffold

Tao Li; Nathaniel L. Rosi

doi:10.1039/C3CC47031H

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Screening and evaluating aminated cationic functional moieties for potential CO₂ capture applications using an anionic MOF scaffold†

Tao Li^b and Nathaniel L. Rosi*^ab

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* Corresponding authors

^a United States Department of Energy, National Energy Technology Laboratory, 626 Cochrans Mill Road, Pittsburgh, Pennsylvania 15236, USA

^b Department of Chemistry, University of Pittsburgh, 219 Parkman Ave, Pittsburgh, Pennsylvania 15260, USA
E-mail: nrosi@pitt.edu

Abstract

Three cations with different amine density, guanidinium, aminoguanidinium, and diaminoguanidinium, were loaded into anionic bio-MOF-1via cation-exchange. The structures and compositions of the cation-exchange products were characterized, and their N₂ and CO₂ adsorption properties were studied and compared.

This article is part of the themed collection: CO2 Separation, Capture and Reuse

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Article information

DOI: https://doi.org/10.1039/C3CC47031H
Article type: Communication
Submitted: 13 Sep 2013
Accepted: 09 Oct 2013
First published: 28 Oct 2013

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Chem. Commun., 2013,49, 11385-11387

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Screening and evaluating aminated cationic functional moieties for potential CO₂ capture applications using an anionic MOF scaffold

T. Li and N. L. Rosi, Chem. Commun., 2013, 49, 11385 DOI: 10.1039/C3CC47031H

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