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Issue 86, 2013
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2-(Pyridinium-1-yl)-1,1-bis(triflyl)ethanides: structural behaviour and availability as bis(triflyl)ethylating reagents

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Abstract

Stable and easy-to-handle zwitterions containing carbanion and pyridinium moieties were synthesized, and their structural studies by both X-ray crystallography and theoretical methods revealed the stereoelectronic effect in the zwitterionic ‘C–C–N+’ system.

Graphical abstract: 2-(Pyridinium-1-yl)-1,1-bis(triflyl)ethanides: structural behaviour and availability as bis(triflyl)ethylating reagents

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Publication details

The article was received on 12 Aug 2013, accepted on 03 Sep 2013 and first published on 05 Sep 2013


Article type: Communication
DOI: 10.1039/C3CC46171H
Citation: Chem. Commun., 2013,49, 10091-10093
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    2-(Pyridinium-1-yl)-1,1-bis(triflyl)ethanides: structural behaviour and availability as bis(triflyl)ethylating reagents

    H. Yanai, Y. Takahashi, H. Fukaya, Y. Dobashi and T. Matsumoto, Chem. Commun., 2013, 49, 10091
    DOI: 10.1039/C3CC46171H

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