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Issue 91, 2013
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The crucial role of a Ni(I) intermediate in Ni-catalyzed carboxylation of aryl chloride with CO2: a theoretical study

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Abstract

In Ni(0)-catalyzed carboxylation reaction of aryl chloride with CO2, the formation of a Ni(I) species is crucial, because the CO2 insertion into the Ni(I)–Ph bond easily occurs but that into the Ni(II)–Ph bond cannot. This is a key point of this successful carboxylation reaction.

Graphical abstract: The crucial role of a Ni(i) intermediate in Ni-catalyzed carboxylation of aryl chloride with CO2: a theoretical study

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Publication details

The article was received on 31 Jul 2013, accepted on 25 Sep 2013 and first published on 26 Sep 2013


Article type: Communication
DOI: 10.1039/C3CC45836A
Citation: Chem. Commun., 2013,49, 10715-10717
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    The crucial role of a Ni(I) intermediate in Ni-catalyzed carboxylation of aryl chloride with CO2: a theoretical study

    F. B. Sayyed, Y. Tsuji and S. Sakaki, Chem. Commun., 2013, 49, 10715
    DOI: 10.1039/C3CC45836A

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