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Issue 78, 2013
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Stereochemical lability of azatitanacyclopropanes: dynamic kinetic resolution in reductive cross-coupling reactions with allylic alcohols

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Abstract

Azatitanacyclopropanes (titanaziridines) are shown to be stereochemically labile under reaction conditions for reductive cross-coupling. This fundamental property has been employed to realize highly selective asymmetric coupling reactions with allylic alcohols that proceed by dynamic kinetic resolution.

Graphical abstract: Stereochemical lability of azatitanacyclopropanes: dynamic kinetic resolution in reductive cross-coupling reactions with allylic alcohols [ ]

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Publication details

The article was received on 23 Jul 2013, accepted on 13 Aug 2013 and first published on 21 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC45607B
Citation: Chem. Commun., 2013,49, 8857-8859
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    Stereochemical lability of azatitanacyclopropanes: dynamic kinetic resolution in reductive cross-coupling reactions with allylic alcohols

    D. Yang and G. C. Micalizio, Chem. Commun., 2013, 49, 8857
    DOI: 10.1039/C3CC45607B

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