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[1,5]-Brook rearrangement: an overlooked but valuable silyl migration to synthesize configurationally defined vinylsilane. The unique steric and electronic effects of geminal bis(silane)

Lu Gao,a   Ji Lu,a   Zhenlei Song,*ab   Xinglong Lin,a   Yongjin Xua and   Zhiping Yina  
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Corresponding authors
Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, Department of Medicinal Chemistry, West China School of Pharmacy, Sichuan University, Chengdu, China
State Key Laboratory of Biotherapy, West China Hospital, Sichuan University, Chengdu, China
Chem. Commun., 2013,49, 8961-8963

DOI: 10.1039/C3CC45002C
Received 04 Jul 2013, Accepted 31 Jul 2013
First published online 01 Aug 2013
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