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[1,5]-Brook rearrangement: an overlooked but valuable silyl migration to synthesize configurationally defined vinylsilane. The unique steric and electronic effects of geminal bis(silane)

Lu Gao,a   Ji Lu,a   Zhenlei Song,*ab   Xinglong Lin,a   Yongjin Xua and   Zhiping Yina  
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Corresponding authors
a
Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, Department of Medicinal Chemistry, West China School of Pharmacy, Sichuan University, Chengdu, China
E-mail: zhenleisong@scu.edu.cn
b
State Key Laboratory of Biotherapy, West China Hospital, Sichuan University, Chengdu, China
Chem. Commun., 2013,49, 8961-8963

DOI: 10.1039/C3CC45002C
Received 04 Jul 2013, Accepted 31 Jul 2013
First published online 01 Aug 2013
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