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Issue 73, 2013
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Enhancement of cyclization quantum yields of perfluorodiarylethenes via weak intramolecular interactions

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Abstract

The weak intramolecular F⋯N and S⋯N interactions in the novel pyridine-containing perfluorodiarylethenes achieved high cyclization quantum yields in solutions. While the F⋯N interactions stabilize the photoreactive conformation, the S⋯N contacts contribute from the energetic aspect.

Graphical abstract: Enhancement of cyclization quantum yields of perfluorodiarylethenes via weak intramolecular interactions

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Publication details

The article was received on 10 Jun 2013, accepted on 09 Jul 2013 and first published on 10 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC44348E
Citation: Chem. Commun., 2013,49, 8036-8038
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    Enhancement of cyclization quantum yields of perfluorodiarylethenes via weak intramolecular interactions

    S. Pu, C. Zheng, Q. Sun, G. Liu and C. Fan, Chem. Commun., 2013, 49, 8036
    DOI: 10.1039/C3CC44348E

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