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Issue 68, 2013
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Iridium(I)-catalyzed vinylic C–H borylation of 1-cycloalkenecarboxylates with bis(pinacolato)diboron

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Abstract

Ir(I)-catalyzed C–H borylation of 1-cycloalkenecarboxylic derivatives with bis(pinacolato)diboron affords various alkenylboronates with functional groups in excellent yields. This reaction was also used in a one-pot borylation/Suzuki–Miyaura cross-coupling procedure.

Graphical abstract: Iridium(i)-catalyzed vinylic C–H borylation of 1-cycloalkenecarboxylates with bis(pinacolato)diboron

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Publication details

The article was received on 03 Jun 2013, accepted on 26 Jun 2013 and first published on 27 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC44149K
Citation: Chem. Commun., 2013,49, 7546-7548
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    Iridium(I)-catalyzed vinylic C–H borylation of 1-cycloalkenecarboxylates with bis(pinacolato)diboron

    I. Sasaki, H. Doi, T. Hashimoto, T. Kikuchi, H. Ito and T. Ishiyama, Chem. Commun., 2013, 49, 7546
    DOI: 10.1039/C3CC44149K

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