Issue 74, 2013

A bifunctional palladium/acid solid catalyst performs the direct synthesis of cyclohexylanilines and dicyclohexylamines from nitrobenzenes

Abstract

Nitroderivatives are transformed to cyclohexylanilines at room temperature in good yields and selectivity via a hydrogenation-amine coupling cascade reaction using Pd nanoparticles on carbon as a catalyst and a Brönsted acid.

Graphical abstract: A bifunctional palladium/acid solid catalyst performs the direct synthesis of cyclohexylanilines and dicyclohexylamines from nitrobenzenes

Supplementary files

Article information

Article type
Communication
Submitted
30 May 2013
Accepted
17 Jul 2013
First published
18 Jul 2013

Chem. Commun., 2013,49, 8160-8162

A bifunctional palladium/acid solid catalyst performs the direct synthesis of cyclohexylanilines and dicyclohexylamines from nitrobenzenes

P. Rubio-Marqués, A. Leyva-Pérez and A. Corma, Chem. Commun., 2013, 49, 8160 DOI: 10.1039/C3CC44064H

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