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Issue 67, 2013
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Ionic conductivity of [Li+@C60](PF6) in organic solvents and its electrochemical reduction to Li+@C60˙

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Abstract

The ionic conductivity of [Li+@C60](PF6) was measured in o-dichlorobenzene, and found to be higher than that of TBA+PF6. Electrochemical reduction of [Li+@C60](PF6) without any supporting electrolyte gave the monovalent radical anion Li+@C60˙, as confirmed by the characteristic ESR signal and NIR absorption band.

Graphical abstract: Ionic conductivity of [Li+@C60](PF6−) in organic solvents and its electrochemical reduction to Li+@C60˙−

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Publication details

The article was received on 24 May 2013, accepted on 26 Jun 2013 and first published on 27 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC43901A
Citation: Chem. Commun., 2013,49, 7376-7378
  • Open access: Creative Commons BY-NC license
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    Ionic conductivity of [Li+@C60](PF6) in organic solvents and its electrochemical reduction to Li+@C60˙

    H. Ueno, K. Kokubo, Y. Nakamura, K. Ohkubo, N. Ikuma, H. Moriyama, S. Fukuzumi and T. Oshima, Chem. Commun., 2013, 49, 7376
    DOI: 10.1039/C3CC43901A

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