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Issue 72, 2013
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Easy access to enamides: a mild nickel-catalysed alkene isomerization of allylamides

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Abstract

The first Ni-catalysed alkene isomerization of allylamides for the synthesis of enamides was demonstrated. Various substituted N-allylamides were found to be suitable substrates for this isomerization. Isotopic labelling experiments showed that it is an intramolecular hydrogen transfer process.

Graphical abstract: Easy access to enamides: a mild nickel-catalysed alkene isomerization of allylamides

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Publication details

The article was received on 23 May 2013, accepted on 28 Jun 2013 and first published on 01 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC43875A
Citation: Chem. Commun., 2013,49, 7923-7925
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    Easy access to enamides: a mild nickel-catalysed alkene isomerization of allylamides

    L. Wang, C. Liu, R. Bai, Y. Pan and A. Lei, Chem. Commun., 2013, 49, 7923
    DOI: 10.1039/C3CC43875A

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