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Issue 75, 2013
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Isolation of a MnIV acylperoxo complex and its monooxidation ability

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Abstract

The first example of monooxygenation by a high-valent MnIV complex with a peroxide is described. A key MnIV acylperoxo intermediate, which uses m-chloroperoxybenzoic acid as the oxygen donor, is directly observed by electro-spray ionization mass spectrometry and resonance Raman spectroscopy.

Graphical abstract: Isolation of a MnIV acylperoxo complex and its monooxidation ability

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Publication details

The article was received on 09 May 2013, accepted on 17 Jul 2013 and first published on 09 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC43447H
Citation: Chem. Commun., 2013,49, 8356-8358
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    Isolation of a MnIV acylperoxo complex and its monooxidation ability

    T. Kikunaga, T. Matsumoto, T. Ohta, H. Nakai, Y. Naruta, K. Ahn, Y. Watanabe and S. Ogo, Chem. Commun., 2013, 49, 8356
    DOI: 10.1039/C3CC43447H

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