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Issue 60, 2013
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Alcohol assisted C–C bond breaking: copper-catalyzed deacetylative α-arylation of β-keto esters and amides

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Abstract

A method of alcohol-assisted copper-catalyzed highly selective deacetylative α-arylation of β-keto esters and amides has been demonstrated, which illustrated an efficient example of achieving α-aryl esters and amides. From the synthetic point of view, this arylation protocol is general and practical, representing a simple way to produce α-arylated carbonyl compounds from basic starting materials at low cost.

Graphical abstract: Alcohol assisted C–C bond breaking: copper-catalyzed deacetylative α-arylation of β-keto esters and amides

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Publication details

The article was received on 03 May 2013, accepted on 04 Jun 2013 and first published on 04 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC43279C
Citation: Chem. Commun., 2013,49, 6767-6769
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    Alcohol assisted C–C bond breaking: copper-catalyzed deacetylative α-arylation of β-keto esters and amides

    J. Ke, C. He, H. Liu, H. Xu and A. Lei, Chem. Commun., 2013, 49, 6767
    DOI: 10.1039/C3CC43279C

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