Issue 49, 2013
From the journal:

Chemical Communications

Angular dependence of the exchange interaction in fluoride-bridged GdIII–CrIII complexes†

Saurabh Kumar Singh,‡a   Kasper S. Pedersen,‡b   Marc Sigrist,bc   Christian Aa. Thuesen,b   Magnus Schau-Magnussen,b   Hannu Mutka,c   Stergios Piligkos,b   Høgni Weihe,b   Gopalan Rajaraman*a  and  Jesper Bendix*b  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, India
E-mail: rajaraman@chem.iitb.ac.in
Fax: +91-22-2576-7152
Tel: +91-22-2576-7183

b Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark
E-mail: bendix@kiku.dk
Fax: +45 35320214
Tel: +45 3520111

c Institut Laue-Langevin, 38042 Grenoble Cedex 9, France

Abstract

The observed angular variation of the magnetic exchange coupling parameter in a series of fluoride-bridged chromium(III)–gadolinium(III) complexes is explained by DFT calculations.

Graphical abstract: Angular dependence of the exchange interaction in fluoride-bridged GdIII–CrIII complexes

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Article information

DOI
https://doi.org/10.1039/C3CC42552E
Article type
Communication
Submitted
08 Apr 2013
Accepted
01 May 2013
First published
01 May 2013
This article is Open Access
Creative Commons BY license

Chem. Commun., 2013,49, 5583-5585

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Angular dependence of the exchange interaction in fluoride-bridged GdIII–CrIII complexes

S. K. Singh, K. S. Pedersen, M. Sigrist, C. Aa. Thuesen, M. Schau-Magnussen, H. Mutka, S. Piligkos, H. Weihe, G. Rajaraman and J. Bendix, Chem. Commun., 2013, 49, 5583 DOI: 10.1039/C3CC42552E

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