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Issue 52, 2013
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Palladium-catalysed aerobic oxidative Heck-type alkenylation of Csp3–H for pyrrole synthesis

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Abstract

The first palladium-catalysed aerobic oxidative intramolecular alkenylation of Csp3–H bonds was described. The reaction conditions were mild and molecular oxygen was used as the terminal oxidant. Kinetic studies showed that the Csp3–H metallation step was a slow step.

Graphical abstract: Palladium-catalysed aerobic oxidative Heck-type alkenylation of Csp3–H for pyrrole synthesis

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Publication details

The article was received on 29 Mar 2013, accepted on 07 May 2013 and first published on 09 May 2013


Article type: Communication
DOI: 10.1039/C3CC42307G
Citation: Chem. Commun., 2013,49, 5853-5855
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    Palladium-catalysed aerobic oxidative Heck-type alkenylation of Csp3–H for pyrrole synthesis

    L. Meng, K. Wu, C. Liu and A. Lei, Chem. Commun., 2013, 49, 5853
    DOI: 10.1039/C3CC42307G

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