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Issue 69, 2013
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Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity

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Abstract

A new imidazolate-4-amide-5-imidate based MOF, IFP-7, is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO2 sorption over N2 and CH4 gases.

Graphical abstract: Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity

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Publication details

The article was received on 26 Mar 2013, accepted on 28 Jun 2013 and first published on 28 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC42156B
Citation: Chem. Commun., 2013,49, 7599-7601
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    Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity

    S. S. Mondal, A. Bhunia, I. A. Baburin, C. Jäger, A. Kelling, U. Schilde, G. Seifert, C. Janiak and H. Holdt, Chem. Commun., 2013, 49, 7599
    DOI: 10.1039/C3CC42156B

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