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Issue 44, 2013
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Solvent-induced lone pair activity tuning and vapoluminescence in a Pt2Pb cluster

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Abstract

We report a novel cluster, [{Pt(C6F5)(bzq)}2Pb(Spy)2] 1, that displays reversible vapoluminescence to specific organic vapours; this behaviour can be related to the stereochemical activity of the lone pair around the PbII in the ground state and to the distinct distortion of the coordination environment (1 and 1solvent) upon photoexcitation.

Graphical abstract: Solvent-induced lone pair activity tuning and vapoluminescence in a Pt2Pb cluster

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Publication details

The article was received on 04 Mar 2013, accepted on 11 Apr 2013 and first published on 11 Apr 2013


Article type: Communication
DOI: 10.1039/C3CC41638K
Citation: Chem. Commun., 2013,49, 5067-5069
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    Solvent-induced lone pair activity tuning and vapoluminescence in a Pt2Pb cluster

    J. R. Berenguer, E. Lalinde, A. Martín, M. Teresa Moreno, S. Ruiz, S. Sánchez and H. R. Shahsavari, Chem. Commun., 2013, 49, 5067
    DOI: 10.1039/C3CC41638K

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