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Issue 44, 2013
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Total synthesis of (8R,6′R)-peridinin-5,8-furanoxide

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Abstract

The first total synthesis of (8R,6′R)-peridinin-5,8-furanoxide, a C37 xanthophyll norcarotenoid, has been achieved. The key steps of the synthetic sequence are a Julia–Kocienski condensation and a late stage stereoretentive Stille cross-coupling of an iodoallene.

Graphical abstract: Total synthesis of (8R,6′R)-peridinin-5,8-furanoxide

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Publication details

The article was received on 28 Feb 2013, accepted on 11 Apr 2013 and first published on 15 Apr 2013


Article type: Communication
DOI: 10.1039/C3CC41552J
Citation: Chem. Commun., 2013,49, 5043-5045
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    Total synthesis of (8R,6′R)-peridinin-5,8-furanoxide

    L. Otero, B. Vaz, R. Álvarez and Á. R. de Lera, Chem. Commun., 2013, 49, 5043
    DOI: 10.1039/C3CC41552J

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