Issue 44, 2013
From the journal:

Chemical Communications

Total synthesis of (8R,6′R)-peridinin-5,8-furanoxide†

Leticia Otero,a   Belén Vaz,a   Rosana Álvarez*a  and  Ángel R. de Lera*a  

* Corresponding authors

a Department of Organic Chemistry As Lagoas-Marcosende, Universidade de Vigo, 36315 Vigo, Spain
E-mail: rar@uvigo.es, qolera@uvigo.es
Web: http://webs.uvigo.es/delera/index.html
Fax: +34 986 818622

Abstract

The first total synthesis of (8R,6′R)-peridinin-5,8-furanoxide, a C37 xanthophyll norcarotenoid, has been achieved. The key steps of the synthetic sequence are a Julia–Kocienski condensation and a late stage stereoretentive Stille cross-coupling of an iodoallene.

Graphical abstract: Total synthesis of (8R,6′R)-peridinin-5,8-furanoxide

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Article information

DOI
https://doi.org/10.1039/C3CC41552J
Article type
Communication
Submitted
28 Feb 2013
Accepted
11 Apr 2013
First published
15 Apr 2013

Chem. Commun., 2013,49, 5043-5045

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Total synthesis of (8R,6′R)-peridinin-5,8-furanoxide

L. Otero, B. Vaz, R. Álvarez and Á. R. de Lera, Chem. Commun., 2013, 49, 5043 DOI: 10.1039/C3CC41552J

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