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Issue 34, 2013
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Quantifying magnetic exchange in doubly-bridged Cu–X2–Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF2(pyrazine)

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Abstract

Solid state techniques involving pressure and temperature have been used to synthesize the fluoride member of the CuX2(pyrazine) (X = F, Cl, Br) family of coordination polymers that cannot be crystallized by solution methods. CuF2(pyrazine) exhibits unique trans doubly-bridged Cu–F2–Cu chains that provide an opportunity to quantify magnetic superexchange in an isostructural Cu–X2–Cu series.

Graphical abstract: Quantifying magnetic exchange in doubly-bridged Cu–X2–Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF2(pyrazine)

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Publication details

The article was received on 22 Feb 2013, accepted on 15 Mar 2013 and first published on 20 Mar 2013


Article type: Communication
DOI: 10.1039/C3CC41394B
Citation: Chem. Commun., 2013,49, 3558-3560
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    Quantifying magnetic exchange in doubly-bridged Cu–X2–Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF2(pyrazine)

    S. H. Lapidus, J. L. Manson, J. Liu, M. J. Smith, P. Goddard, J. Bendix, C. V. Topping, J. Singleton, C. Dunmars, J. F. Mitchell and J. A. Schlueter, Chem. Commun., 2013, 49, 3558
    DOI: 10.1039/C3CC41394B

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