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Issue 44, 2013
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Catalytic hydrogen production by a Ni–Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step

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Abstract

A combined electrochemical and theoretical study suggests that hydrogen evolution from weak acids catalyzed by a structural mimic of the active site of NiFe hydrogenases [Ni(xbsms)Ru(C6Me6)Cl]+ proceeds through proton-coupled electron transfer steps.

Graphical abstract: Catalytic hydrogen production by a Ni–Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step

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Publication details

The article was received on 05 Feb 2013, accepted on 05 Apr 2013 and first published on 23 Apr 2013


Article type: Communication
DOI: 10.1039/C3CC40987B
Citation: Chem. Commun., 2013,49, 5004-5006
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    Catalytic hydrogen production by a Ni–Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step

    S. Canaguier, V. Fourmond, C. U. Perotto, J. Fize, J. Pécaut, M. Fontecave, M. J. Field and V. Artero, Chem. Commun., 2013, 49, 5004
    DOI: 10.1039/C3CC40987B

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