Cu(OTf)2 catalysed [6+2] cycloaddition reaction for the synthesis of highly substituted pyrrolo[1,2-a]indoles: rapid construction of the yuremamine core

Dattatraya H. Dethe; Raghavender Boda; Saikat Das

doi:10.1039/C3CC40617B

Cu(OTf)₂ catalysed [6+2] cycloaddition reaction for the synthesis of highly substituted pyrrolo[1,2-a]indoles: rapid construction of the yuremamine core

Dattatraya H. Dethe,*^a Raghavender Boda^a and Saikat Das^a

* Corresponding authors

^a Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India
E-mail: ddethe@iitk.ac.in
Fax: +91-512-2597436
Tel: +91-512-2596537

Abstract

Lewis acid catalysed [6+2] cycloaddition reaction for the synthesis of pyrrolo[1,2-a]indoles generating three contiguous stereocenters in a highly regio- and diastereoselective manner has been developed and further applied for the construction of the fully functionalized tricyclic core of yuremamine.

Supplementary files

Publication details

The article was received on 24 Jan 2013, accepted on 26 Feb 2013 and first published on 26 Feb 2013

Article type: Communication

DOI: 10.1039/C3CC40617B

Citation: Chem. Commun., 2013,49, 3260-3262

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Cu(OTf)₂ catalysed [6+2] cycloaddition reaction for the synthesis of highly substituted pyrrolo[1,2-a]indoles: rapid construction of the yuremamine core

D. H. Dethe, R. Boda and S. Das, Chem. Commun., 2013, 49, 3260
DOI: 10.1039/C3CC40617B
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Chemical Communications

Cu(OTf)₂ catalysed [6+2] cycloaddition reaction for the synthesis of highly substituted pyrrolo[1,2-a]indoles: rapid construction of the yuremamine core

Abstract

Supplementary files

Publication details

Cu(OTf)₂ catalysed [6+2] cycloaddition reaction for the synthesis of highly substituted pyrrolo[1,2-a]indoles: rapid construction of the yuremamine core

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