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Issue 24, 2013
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Postsynthetic functionalization of 3D covalent organic frameworks

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Abstract

We demonstrate a tandem truncation–functionalization strategy using the 3D covalent organic framework, COF-102. Allyl groups incorporated within the pore walls were subjected to thiol–ene coupling conditions, achieving high conversions and maintaining the crystallinity and permanent porosity of the parent framework.

Graphical abstract: Postsynthetic functionalization of 3D covalent organic frameworks

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Publication details

The article was received on 16 Jan 2013, accepted on 08 Feb 2013 and first published on 11 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC40358K
Citation: Chem. Commun., 2013,49, 2457-2459
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    Postsynthetic functionalization of 3D covalent organic frameworks

    D. N. Bunck and W. R. Dichtel, Chem. Commun., 2013, 49, 2457
    DOI: 10.1039/C3CC40358K

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