Issue 24, 2013
From the journal:

Chemical Communications

Postsynthetic functionalization of 3D covalent organic frameworks†

David N. Buncka  and  William R. Dichtel*a  

* Corresponding authors

a Department of Chemistry and Chemical Biology, Cornell University, Ithaca, USA
E-mail: wdichtel@cornell.edu
Fax: +1 607-255-4137
Tel: +1 607-254-2356

Abstract

We demonstrate a tandem truncation–functionalization strategy using the 3D covalent organic framework, COF-102. Allyl groups incorporated within the pore walls were subjected to thiol–ene coupling conditions, achieving high conversions and maintaining the crystallinity and permanent porosity of the parent framework.

Graphical abstract: Postsynthetic functionalization of 3D covalent organic frameworks

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Article information

DOI
https://doi.org/10.1039/C3CC40358K
Article type
Communication
Submitted
16 Jan 2013
Accepted
08 Feb 2013
First published
11 Feb 2013

Chem. Commun., 2013,49, 2457-2459

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Postsynthetic functionalization of 3D covalent organic frameworks

D. N. Bunck and W. R. Dichtel, Chem. Commun., 2013, 49, 2457 DOI: 10.1039/C3CC40358K

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