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Issue 26, 2013
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Stepwise ligand transformations through [2+2] photodimerization and hydrothermal in situ oxidation reactions

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Abstract

The SCSC transformation of a 1D polymer [Cd(1,3-bdc)(4-spy)2]n produced a 2D polymer [Cd(1,3-bdc)(4-spy)(HT-ppcb)0.5]n through the [2+2] photodimerization reaction. Hydrothermal reactions of HT-ppcb with CdCl2, 1,3-H2bdc and H2O2 afforded another 2D polymer {[Cd(H2O)(1,3-bdc)(bpbpf)]·H2O}n in which HT-ppcb underwent in situ oxidation to form a unique furan-based ligand bpbpf.

Graphical abstract: Stepwise ligand transformations through [2+2] photodimerization and hydrothermal in situ oxidation reactions

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Publication details

The article was received on 30 Dec 2012, accepted on 12 Feb 2013 and first published on 14 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC39286D
Citation: Chem. Commun., 2013,49, 2682-2684
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    Stepwise ligand transformations through [2+2] photodimerization and hydrothermal in situ oxidation reactions

    D. Liu, J. Lang and B. F. Abrahams, Chem. Commun., 2013, 49, 2682
    DOI: 10.1039/C3CC39286D

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