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Issue 22, 2013
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P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes

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Abstract

The two new 3d/4f polyphosphide complexes [(Cp*Fe)2P10{Sm(η5-C5Me4R)2}2] (Cp* = η5-C5Me5; R = Me, nPr) were prepared by reductive dimerization of [Cp*Fe(η5-P5)] with samarocenes. They are the first P10 bridging 3d/4f metal complexes and the first examples of reductive coupling of polyphosphide complexes by divalent lanthanides.

Graphical abstract: P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes

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Publication details

The article was received on 10 Dec 2012, accepted on 18 Jan 2013 and first published on 05 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC38841G
Citation: Chem. Commun., 2013,49, 2183-2185
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    P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes

    T. Li, M. T. Gamer, M. Scheer, S. N. Konchenko and P. W. Roesky, Chem. Commun., 2013, 49, 2183
    DOI: 10.1039/C3CC38841G

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