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Issue 19, 2013
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N,N-Chelate-control on the regioselectivity in acetate-assisted C–H activation

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Abstract

Bidentate N,N-pyridylimine or N,N-pyridylamine donors are effective chelating ligands for regiospecific C–H activation at the peri-(C8)-position of a naphthyl ring on reaction with palladium(II) acetate; DFT calculations show N,N-chelates bias the cyclopalladation towards 6-membered ring products.

Graphical abstract: N,N-Chelate-control on the regioselectivity in acetate-assisted C–H activation

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Publication details

The article was received on 04 Dec 2012, accepted on 18 Jan 2013 and first published on 21 Jan 2013


Article type: Communication
DOI: 10.1039/C3CC38697J
Citation: Chem. Commun., 2013,49, 1918-1920
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    N,N-Chelate-control on the regioselectivity in acetate-assisted C–H activation

    W. B. Cross, E. G. Hope, Y. Lin, S. A. Macgregor, K. Singh, G. A. Solan and N. Yahya, Chem. Commun., 2013, 49, 1918
    DOI: 10.1039/C3CC38697J

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